Replacing Fossil Fuels

If you follow the public debate over global warming, you get the impression that generating electricity is the only problem. Actually, electricity is the easy part of the problem because we can generate all the electricity we need from non-fossil energy sources. Considering the externalized costs of fossil fuels, the non-fossil sources are even cost-effective.

The hard part of the problem is motor fuels. We don't have a good substitute in place. Biofuels won't ever supply a major part of our motor fuels, for reasons we've discussed before. But take heart. Two chemists at Los Alamos National Laboratory have devised a process using current technology that could replace petroleum as as source. F. Jeffrey Martin and William L. Kubic have published Green Freedom: A Concept for Producing Carbon-Neutral Synthetic Fuels and Chemicals (Patent Pending).


A Simple Description

As you can imagine, turning atmospheric CO2 into gasoline takes a huge amount of energy. In this process, the energy inputs are in the form of heat and electricity. Lots of both.

The electricity could come from a number of sources, but the process is most effective if the electricity supply is steady, which effectively limits it to nuclear. That's just as well, though, because the CO2 capture requires spraying a potassium-carbonate solution into an air stream. That requires something very much like a wet cooling tower, so the wet cooling tower for the nuclear plant can do double duty as a CO2 collector.

Once the CO2 is collected, it can be extracted from the solution by an electrolytic process, originated by Martin and Kubic. They claim that this is their chief innovation and that all the other features of the process are standard to the chemical industry. The electrolytic process is more energy-efficient than other means of separating the CO2, and generates hydrogen at the same time, reducing the amount of hydrogen that has to be generated elsewhere.

In their baseline design, Martin and Kubic propose to use water electrolysis for generating the additional hydrogen needed. They chose this because nuclear plants in the US are all capable of providing the electricity needed. As they point out, more-recent technology can improve efficiencies substantially. Steam electrolysis consumes less energy and advanced nuclear reactors can generate hydrogen thermochemically; this last technique can be essentially 100% efficient, since the leftover heat can generate electricity.

Once the hydrogen is generated, commercially-tested processes can be used for converting CO2 and hydrogen into methanol, and for converting methanol into gasoline. Alternatively, hydrogen, CO2, and steam can be combined over catalysts in the Fisher-Tropsch process to produce any kind of hydrocarbon compound, including diesel oil and aviation fuel.


Practicality

As the authors take pains to make clear, the process depends only on equipment in commercial use today. There are no technological barriers to implementing it. There is a cost consideration, however. Their calculations show that the gasoline could be sold at the pump for $4.60 per gallon. Since we're dealing here with known technology they probably are not understating it by much, taking into account that projects of all kinds end up costing more than the planners expected.

But there are ample reasons for believing the actual costs would be lower. As they explain, newer technology will improve efficiencies considerably. Moreover, their analysis assumes their nuclear plant, which comprises the main capital cost, would be dedicated to producing hydrocarbon fuel. In practice, the nuclear plant will sell electricity during times of peak demand, especially when renewable energy is in short supply. This will become more apparent when fossil-fired power plants are phased out and all electricity depends on renewable and nuclear sources. We can look forward to an economy in which nuclear plants produce all our hydrocarbon fuels during off-peak hours. This sharing of costs will greatly reduce the cost of producing liquid fuels.


Looking Ahead

What we can say for sure is that it will take a massive energy investment to free the world from dependence on petrofuels. Straight hydrogen doesn't look promising because of the difficulty of onboard storage and because the inevitable leaks will threaten the ozone layer. Batteries for powering freight-hauling trucks don't seem like a reasonable hope, given the paltry improvements batteries have seen in the last few decades. Biofuels won't do the job, as discussed earlier. Since this process is already practical, it's not much of a stretch to predict that something very similar will be our fuel source in the future.

The Academic Approach to Anti-Nuclearism

For a long time there's been a belief among anti-nukes that you can prove anything if you write enough. You just have to beat science with statistical analysis and smother it with paper.

This came up again on another blog, which uses a lot of scientific language but is dedicated to the proposition that the laws of nature can be over-ridden if they're inconvenient.

In this case, the writer of the article is determined to show that part-time energy sources can provide full-time power, if you just do enough mathematical manipulations.

First he cites "Supplying Baseload Power and Reducing Transmission Requirements by Interconnecting Wind Farms" by Cristina L. Archer and Mark Z. Jacobson, which argues that if enough wind turbines are interconnected they can provide base-load power. According to the authors, the part of the average output that can be considered 87.5% reliable is between 33% and 47%, depending on how many wind turbines are interconnected. However, the area they studied, centered on the Texas and Oklahoma panhandles, has the most reliable winds in the US and their results don't translate to the country as a whole. Even so, they show that wind farms would have to be oversized by a factor of at least 2. They elect to call it base load, but that's not appropriate. It only can be base load if there is also some form of load-following power.

That's a problem. Without fossil fuel and nuclear energy, load following is limited to whatever hydro and pumped storage can be made available, and at most that can only be a few percent.

The article writer also cites "Improving the Technical, Environmental and Social Performance of Wind Energy Systems Using Biomass-Based Energy Storage" by Paul Denholm, which recognizes that problem and suggests using biofuels for backup. But there are a couple of problems here. One is that nowhere does he consider the fuel required to grow the biomass and convert it into biofuel. Currently, it takes up to a gallon of fuel to produce a gallon of fuel, and certainly a big part of a gallon. It seems unlikely that it will ever take no fuel to produce a gallon of fuel. In the absence of better information, his study has to be considered extremely optimistic.

His optimistic estimate is that it would take 6.9 hectares or .0266 sq mi to produce biofuels that would generate 1000 MWH per year. The US uses 4 billion MWH/year, so the area required would be 106,400 square miles, out of 650,000 square miles of arable land. Suppose wind energy allows us to reduce that in half, which would require a half-million 1.5 MW wind turbines (rotor height = 450 feet!); we still need 53,000 square miles. Since we're using almost all the arable land for food and fiber, it's not clear where the 53,000 square miles will come from. Also, to farm land of this magnitude means using less-productive land. He assumes 11.3 tonnes/hectare yields, which would require prime Iowa land, so the land areas would be much greater and very likely would require irrigation, for which water will not be available. That's enough trouble already, but consider that the need for motor fuels will vastly outweigh the need for bio-electricity, because there is another, better, way to generate electricity but no alternative way to produce non-fossil motor fuels.

So we're still where we've always been. Wind energy doesn't work without a backup, and biofuels won't provide the backup.

As we explained in an earlier article, nuclear energy allows solar and wind to play their maximum part in providing electricity. Further, it allows them to contribute efficiently to the production of hydrogen, by taking some load off the nuclear plants. This is the kind of solution that will minimize global warming. Trying to paper over the limitations of renewable sources with scientific-looking obfuscations, if it's successful, can only keep the world on its present reckless path to self-destruction.

But anti-nukes don't get this. They believe you can change reality by manipulating data. You want windmills to turn when there's no wind? No problem. Just crank out fifteen pages of equations, tables, diagrams, and charts and they'll turn themselves!